Mercury diffusion in Hg1?xCdxTe

A radiotracer technique has been used to measure both mercury self-diffusion and surface concentration values in bulk and liquid phase epitaxy, LPE, grown Hg_1−xCd_xTe. A high resolution sectioning technique has allowed profiling of thin epitaxial layers in submicron steps. Hg_1-xCd_xTe samples with composition values betweenx _Cd= 0.16 and 0.23 were isothermally annealed in carefully controlled and monitored diffusion con-ditions. Mercury reservoirs containing Hg²⁰³ were used to provide vapour diffusion sources during closed tube isothermal anneals in the temperature range 300° C to 400° C. Evidence has been found which may indicate the presence of two components in the radio-tracer profiles for both bulk and epitaxially grown material. In some cases it was possible to estimate two diffusion coefficients,D ₁andD ₂, from the near surface and deeply penetrating components, respectively. Our results forD ₁andD ₂are compared with other work. For bulk material annealed at 400° C under a saturated mercury pressureD ₁= 2.0 x 10^-12cm²s^-1 andD ₂= 1.1 x 10^-11cm²s⁻¹. Diffusion coefficients at 310° C under saturated mercury pressure, have been measured in bulk and epitaxial material. Close agreement was found between these results with an average value ofD ₁= 1.4 x 10⁻¹³cm²s⁻¹. We believe this to be the first time radiotracer results for epitaxial material have been presented. We have collated diffusion data, as a function of reciprocal temperature, from several workers and suggest there is evidence for a change in the activation energy for mercury diffusion around 350° C. This may be due to a change in the dominant diffusion mechanism.