| Construction of a Ytterbium Supramolecular Compound from 5,5＇-（Buta-diyne- 1,4-diyl）diisophthalic Acid |
| |
| 作者姓名： | WANG Jing ;MU Li ;ZHAO Tingting ;FAN Zhiqiang ;ZHANG Lirong |
| |
| 作者单位： | [1]State Key Laboratory of lnorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, P. R. China,"; [2]School of Bioscience and Technology, Changchun University, Changchun 130022, P. R. China |
| |
| 基金项目： | Supported by the National Natural Science Foundation of China（No.20701015）. |
| |
| 摘 要： | A novel 3D ytterbium supramolecular compound, Yb（HBDDC）（H20）4]·2H2O（1）, was synthesized via 5,5＇-（buta-diyne-1,4-diyl）diisophthalic acid ligand（HaBDDC） under solvothermal conditions. Single-crystal X-ray diffraction analysis reveals that compound 1 crystallizes in triclinic system, PT space group with a=0.71372（14） nm, b=1.0566（2） nm, c=1.7969（4） nm, a=101.01（3）°, β=98.15（3）°, γ=99.17（3）° and V=1.2922（4） nm3. Compound 1 exhi- bits a special infinite 1D chain, which stacks parallel each other in an ABAB sequence, leading to the formation of a 3D supramolecular structure owing to the strong π-π interactions between adjacent phenyl ring groups. Moreover, compound 1 manifests excellent luminescent property.
|
| 关 键 词： | 超分子化合物 超分子结构 布塔 单晶X射线衍射分析 镱 三斜晶系 相互作用 发光特性 |
| 收稿时间： | 2014-05-21 |
Construction of a Ytterbium Supramolecular Compound from 5,5 '-(Buta-diyne-1,4-diyl)diisophthalic Acid |
| |
| WANG Jing,;MU Li,;ZHAO Tingting,;FAN Zhiqiang,;ZHANG Lirong.Construction of a Ytterbium Supramolecular Compound from 5,5 '-(Buta-diyne-1,4-diyl)diisophthalic Acid[J].Chemical Research in Chinese University,2014,30(6):885-888. |
| |
| Authors: | WANG Jing MU Li ZHANG Jian ZHAO Tingting FAN Zhiqiang ZHANG Lirong |
| |
| Institution: | 1. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, P. R. China;
2. School of Bioscience and Technology, Changchun University, Changchun 130022, P. R. China |
| |
| Abstract: | A novel 3D ytterbium supramolecular compound, Yb(HBDDC)(H2O)4]·2H2O(1), was synthesized via 5,5'-(buta-diyne-1,4-diyl)diisophthalic acid ligand(H4BDDC) under solvothermal conditions. Single-crystal X-ray diffraction analysis reveals that compound 1crystallizes in triclinic system, Pī space group with a=0.71372(14) nm, b=1.0566(2) nm, c=1.7969(4) nm, α=101.01(3)°, β=98.15(3)°, γ=99.17(3)° and V=1.2922(4) nm3. Compound 1 exhibits a special infinite 1D chain, which stacks parallel each other in an ABAB sequence, leading to the formation of a 3D supramolecular structure owing to the strong π-π interactions between adjacent phenyl ring groups. Moreover, compound 1 manifests excellent luminescent property. |
| |
| Keywords: | Supramolecular compound Solvothermal condition Ytterbium Luminescent property |
| 本文献已被 维普 万方数据 等数据库收录！ |
| 点击此处可从《高等学校化学研究》浏览原始摘要信息 |
| 点击此处可从《高等学校化学研究》下载免费的PDF全文 |
|
