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Vibrational excitation effects on silane reactivity in its reaction with bromine atoms |
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| Authors: | N K Serdyuk E N Chesnokov and V N Panfilov |
| Institution: | (1) Institute of Chemical Kinetics and Combustion, Novosibirsk, USSR |
| Abstract: | A rate increase of SiH3Br formation in SiH4 photobromination under irradiation by a cw CO2 laser is reported. At low SiH4 pressures ( 1–2 Pa) the radiation effect is shown to be isotope-selective.
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SiH3Br 
