A rapid stereocontrolled synthesis of the 3a-hydroxy-pyrrolo[2,3-b]indole skeleton, a building block for 10b-hydroxy-pyrazino[1',2':1,5]pyrrolo[2,3-b]indole-1,4-diones |
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| Authors: | Ley Steven V Cleator Ed Hewitt Peter R |
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| Institution: | Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge, UK CB2 1EW. svl1000@cam.ac.uk |
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| Abstract: | A two-step selenocyclisation-oxidative deselenaton sequence was used to establish the 3a-hydroxy-pyrrolo2,3-b]indole core; these tricycles were used as effective precursors to 10b-hydroxy-pyrazino1',2':1,5]pyrrolo2,3-b]indole-1,4-diones. |
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