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Mixing properties of tris(2-hydroxyethyl)methylamonium methylsulfate,water, and methanol at 298.15 K. Data treatment using several correlation equations
Authors:Alberto Arce  Ana Soto  Juan Ortega  Gisela Sabater
Institution:1. Departamento de Ingeniería Química, Universidad de Santiago de Compostela, E-15782 Santiago de Compostela, Spain;2. Laboratorio de Termodinámica y Fisicoquímica de Fluidos, Parque Científico-Tecnológico, Universidad de las Palmas de Gran Canaria, E-35071 Canary Islands, Spain
Abstract:Densities, viscosities, and refractive indices at 298.15 K and atmospheric pressure are reported for the binary and ternary mixtures formed by tris(2-hydroxyethyl) methylamonium methylsulfate, water, and methanol. Excess molar volumes and viscosity logarithm variations have been calculated from the physical properties of the pure compounds and their mixtures. The UNIQUAC volume and area parameters have been determined for the tris(2-hydroxyethyl) methylamonium methylsulfate ionic liquid. All properties changes of mixing have been fitted using two polynomial models and the UNIQUAC equation. An evaluation of the correlation capacity has been analyzed for the three models.
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