Oxidative carbon-carbon bond formation via silyl bis-enol ethers: controlled cross-coupling for the synthesis of quaternary centers |
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Authors: | Clift Michael D Taylor Carla N Thomson Regan J |
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Affiliation: | Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208, USA. |
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Abstract: | Unsymmetrical silyl bis-enol ethers have been developed as effective substrates for synthesizing quaternary centers from tetralone derivatives through oxidative carbon-carbon bond formation. The derived products are shown to be highly versatile intermediates that may be used to generate diverse structures such as cyclopentenones, 2H-pyrroles, and spirocyclic pyrrolidines. |
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