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Simultaneous ROMP and ATRP in Aqueous Dispersed Media: A Straightforward Strategy to Prepare Polymer Composite Particles with Original Morphologies |
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| Authors: | Cédric Airaud Emmanuel Ibarboure Cédric Gaillard Valérie Héroguez |
| Institution: | 1. Laboratoire de Chimie des Polymères Organiques, UMR CNRS-ENSCPB-Université de Bordeaux, 16 avenue Pey-Berland, 33607 Pessac Cedex, France;2. INRA-Unité BIA Plateforme BIBS - Microscopie, Rue de la Geraudière. B.P 71627. 44316 Nantes Cedex, France |
| Abstract: | Summary: The simultaneous ring-opening metathesis polymerization of norbornene and atom-transfer radical polymerization of methyl methacrylate is used as a convenient tool to prepare polymer composite particles in a single step and using a single catalyst. The current article reviews the use of miniemulsion and microemulsion conditions to reach this goal. The two developed approaches are assessed on chemical and colloidal levels and the prepared composite particles are scrutinized from a morphological point of view. |
| Keywords: | atom-transfer radical polymerization (ATRP) microemulsion polymerisation miniemulsion polymerization polymer composite particles ring-opening metathesis polymerization (ROMP) |