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Degradation behavior and application of recycled PVC sheet made of floor sheet for railway vehicle
Authors:Mikiya Ito  Kazukiyo Nagai
Institution:a Material Development Division, Railway Technical Research Institute, 2-8-38, Hikari-cho, Kokubunji-shi, Tokyo 185-8540, Japan
b Department of Applied Chemistry, Meiji University, 1-1-1, Higashi-mita, Tama-ku, Kawasaki 214-8571, Japan
Abstract:A floor sheet made of plasticized poly(vinyl chloride) (PVC) is used as interior material for railway vehicle. Some of the floor sheets mainly used in Express and Shinkansen vehicles were layered by vulcanized surface to protect against the fire. Therefore, these floor sheets have been considered as inappropriate material for recycling. In this paper, some varieties of recycled sheets made of these floor sheets have been studied with respect to a long-term stability which is necessary for practical application. Through the weathering test, these recycled sheets indicated suitable mechanical properties for long-term outdoor use; however, at the beginning of weathering test, the elongation was reduced by the rapid flow out of plasticizer. The mechanical strength was closely related to the plasticizer concentration. Based on the plasticizer concentration, the tensile strength could be estimated without dependence of specimen preparations and the slope of the elongation was related to the content of the floor sheet. To prevent flowing out of plasticizer, virgin PVC was laminated to the surface of recycled sheet. The laminated sheet was set up at the outdoor to be used as an anti-weed sheet. For more than five years, the laminated sheet has kept on preventing overgrowth of weed and flow out speed of plasticizer has decreased by the effect of virgin PVC lamination. It is presumable that the laminated sheet was estimated to be used as the anti-weed sheet for more years.
Keywords:Poly(vinyl chloride) (PVC)  Material recycling  Floor sheet for railway vehicle  Long-term stability  Anti-weed sheet
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