Copolymers of methyl methacrylate with some benzanthrone dyes, photo-stabilisers and their combined structures |
| |
Authors: | T.N. Konstantinova R.A. Lazarova |
| |
Affiliation: | Organic Synthesis Department, University of Chemical Technology and Metallurgy, 8 Ohridsky str., Sofia 1756, Bulgaria |
| |
Abstract: | Copolymerisation of methyl methacrylate with nine novel monomer compounds, triazinyl benzanthrone dyes, triazinyl benzotriazole stabilisers and their combined structures, was investigated. Chemical bonding of the compounds in the polymers obtained was confirmed spectrophotometrically. The quantity of the chemically bonded monomer compounds was determined to be over 50%, providing a colour and a fluorescence stable to solvents. Their influence on the rate of the copolymerisation was studied. It was found that the compounds under study did not significantly affect the rate of copolymerisation. A stabilizing effect towards photo-degradation of PMMA was achieved at 0.1 wt.% initial concentration of the compounds, which made them suitable for “one-step” colouration and stabilisation of PMMA. |
| |
Keywords: | Copolymers of MMA Polymerizable benzanthrone dyes Benzotriazole stabilizers and their combined structures One-step coloration and stabilization |
本文献已被 ScienceDirect 等数据库收录! |
|