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Copolymers of methyl methacrylate with some benzanthrone dyes, photo-stabilisers and their combined structures
Authors:T.N. Konstantinova  R.A. Lazarova
Affiliation:Organic Synthesis Department, University of Chemical Technology and Metallurgy, 8 Ohridsky str., Sofia 1756, Bulgaria
Abstract:Copolymerisation of methyl methacrylate with nine novel monomer compounds, triazinyl benzanthrone dyes, triazinyl benzotriazole stabilisers and their combined structures, was investigated. Chemical bonding of the compounds in the polymers obtained was confirmed spectrophotometrically. The quantity of the chemically bonded monomer compounds was determined to be over 50%, providing a colour and a fluorescence stable to solvents. Their influence on the rate of the copolymerisation was studied. It was found that the compounds under study did not significantly affect the rate of copolymerisation. A stabilizing effect towards photo-degradation of PMMA was achieved at 0.1 wt.% initial concentration of the compounds, which made them suitable for “one-step” colouration and stabilisation of PMMA.
Keywords:Copolymers of MMA   Polymerizable benzanthrone dyes   Benzotriazole stabilizers and their combined structures   One-step coloration and stabilization
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