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Phase equilibria in the neodymium-barium-copper-oxygen system at low oxygen pressures
Authors:V A Lysenko
Institution:(1) Faculty of Chemistry, Moscow State University, Moscow, Russia
Abstract:The analytic equations for the Gibbs energies of Nd-Ba-Cu-O system phases obtained earlier were used to calculate the (1/2)BaCuO2-(1/2)NdCuO2 section of the phase diagram at oxygen partial pressures of 0.01 and 0.001 bar. For p(O2) = 0.01 bar, the coordinates of the nonvariant points of the Nd-Ba-Cu-O system were determined, and the phase diagrams of the (1/8)Ba3Cu5O8-NdO1.5 and (1/4)BaCu3O4-(1/4)BaNd3O5.5 systems were calculated.
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