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Synthesis and crystal structure of a novel two-dimensional network complex [Mn(O_2CCH_2Cl)_2(phen)]_n
引用本文:LI Jun,ZHANG Jinhua,WU Aizhi,XI Yun,GUO Hui & ZHANG Fengxing Department of Chemistry,Northwest University/Shaanxi Province Key Laboratory of Physicoinorganic Chemistry,Xi''''an 710069,China. Synthesis and crystal structure of a novel two-dimensional network complex [Mn(O_2CCH_2Cl)_2(phen)]_n[J]. 中国科学B辑(英文版), 2005, 48(Z1)
作者姓名:LI Jun  ZHANG Jinhua  WU Aizhi  XI Yun  GUO Hui & ZHANG Fengxing Department of Chemistry  Northwest University/Shaanxi Province Key Laboratory of Physicoinorganic Chemistry  Xi''''an 710069  China
作者单位:LI Jun,ZHANG Jinhua,WU Aizhi,XI Yun,GUO Hui & ZHANG Fengxing Department of Chemistry,Northwest University/Shaanxi Province Key Laboratory of Physicoinorganic Chemistry,Xi'an 710069,China
基金项目:the National Natural Science Foundation of China,陕西省自然科学基金
摘    要:A novel two-dimensional network manganese(Ⅱ) polymer complex [Mn(O2CCH2CI)2-(phen)]n has been synthesized and characterized by elemental analysis and IR spectrum. The crystal structure of title complex has also been determined, which is in monoclinic of a space group P21/c with the following unit cell parameters at 294K: a =1.9738(4) nm, b =1.1384(2) nm, c =0.74915(14) nm, V=1.6795(5) nm3, Z= 2.


Synthesis and crystal structure of a novel two-dimensional network complex [Mn(O2CCH2Cl)2(phen)]n
LI Jun,ZHANG Jinhua,WU Aizhi,XI Yun,GUO Hui,ZHANG Fengxing. Synthesis and crystal structure of a novel two-dimensional network complex [Mn(O2CCH2Cl)2(phen)]n[J]. Science in China(Chemistry), 2005, 48(Z1)
Authors:LI Jun  ZHANG Jinhua  WU Aizhi  XI Yun  GUO Hui  ZHANG Fengxing
Affiliation:Department of Chemistry, Northwest University/Shaanxi Province Key Laboratory of Physicoinorganic Chemistry, Xi'an 710069, China
Abstract:A novel two-dimensional network manganese(Ⅱ) polymer complex [Mn(O2CCH2CI)2-(phen)]n has been synthesized and characterized by elemental analysis and IR spectrum. The crystal structure of title complex has also been determined, which is in monoclinic of a space group P21/c with the following unit cell parameters at 294K: a=1.9738(4) nm, b =1.1384(2) nm, c =0.74915(14) nm, V =1.6795(5) nm3, Z= 2.
Keywords:synthesis  polymer  manganese complex  two-dimensional network
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