MIL-103, a 3-D lanthanide-based metal organic framework with large one-dimensional tunnels and a high surface area |
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Authors: | Devic Thomas Serre Christian Audebrand Nathalie Marrot Jérôme Férey Gérard |
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Institution: | Institut Lavoisier, UMR CNRS 8637, Université de Versailles Saint-Quentin-en-Yvelines, 45 avenue des Etats-Unis, 78035 Versailles Cedex, France. ferey@chimie.uvsq.fr |
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Abstract: | A lanthanide-based metal organic framework, formulated Tb(C27H15O6)(H2O).2C6H11OH, has been solvothermally synthesized using the extended rigid tritopic ligand 1,3,5-tribenzoate. Included free solvent could be removed upon heating, and the resulting material presents large 1-D micropores (free diameter = 10 A) and a high surface area (SLangmuir > 1000 m2.g-1). |
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