Carbon-carbon and carbon-heteroatom bond formation on solid phase using cationic iron carbonyl complexes |
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Authors: | Gradén Henrik Olsson Thomas Kann Nina |
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Institution: | Organic Chemistry, Department of Chemical and Biological Engineering, Chalmers University of Technology, SE-41296 G?teborg, Sweden. |
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Abstract: | Iron-mediated methodology for the formation of carbon-carbon and carbon-heteroatom sp(3) bonds on solid phase has been developed. Treatment of a polymer-bound cationic iron cyclohexadienyl complex with carbon, oxygen, nitrogen, and phosphorus nucleophiles, followed by cleavage with amines and subsequent decomplexation, yielded 18 different cyclohexadienoic acid amides of high purity. reaction: see text] |
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