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Haloacetylated enol ethers. 14 [6]. Reaction of β-alkoxyvinyl trifluoromethyl ketones with N-methylhydroxylamine |
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| Authors: | Marcos A P Martins Alex F C Flores Giovani P Bastos Nilo Zanatta Helio G Bonacorso |
| Abstract: | The reaction of a series of β-methoxyvinyl trifluoromethyl ketones CF3COC(R2)?C(OMe)R1, where R1 = Me, -(CH2)3-C3, -CH2)4-C3, Ph and R2 = H, Me, -(CH2)3-C4, -(CH2)4-C4] with N-methylhydroxylamine is reported. The regiochemistry of the reaction are explained by MO calculation data. |
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