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Total Synthesis of (±)-Iridolactone |
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| Authors: | An-Yang Lee Meng-Yang Chang Huo-Mu Tai Nein-Chen Chang |
| Abstract: | A total synthesis of (±)-iridolactone ( 1 ) from bicyclo[2.2.1]ketone 6 is described. Trisubstituted cyclopentenoid aldehyde 7 is a key intermediate. |
| Keywords: | Iridolactone Iridoid Pedicularis-lactone Ningpogenin Tetrahydroanhydrodesoxyaucubigenin Boschnialactone Reductive cyclization |