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Ene Reaction with Pummerer-Type Reaction Intermediate of α-(Methylthio)isobutyl Acetamide: A New Synthesis of Pellitorine |
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| Authors: | Ling-Ching Chen Iou-Jiun Kang Huey-Min Wang |
| Abstract: | Pummerer-type reaction intermediate 2 of α-(methylthio)isobutyl acetamide ( 1 ) has been found to react with 1-alkenes to afford ene adducts 3 . Pellitorine 4 was synthesized from the adduct 3d. |
| Keywords: | Pummerer-type reaction intermediate Phenyliodine(III) bis(trifluoroacetate) Ene reaction |