|
|||||
|
|
Theoretical treatment of first-order reversible reactions occurring in a chromatographic reactor, on the basis of consecutive reactions |
|
| Authors: | R Thede E Below D Haberland S H Langer |
| Institution: | 1. Institute of Physical Chemistry, University of Greifswald, Soldtmannstra?e 23, 17489, Greifswald, Germany 2. Institute of Forensic Medicine, University of Greifswald, Soldtmannstra?e 23, 17489, Greifswald, Germany 3. Department of Chemical Engineering, University of Wisconsin, Madison, WI, USA |
| Abstract: | Summary Analytical peak-shape equations were derived for first-order reversible reactions occurring in a chromatographic reactor by treating the reversible reactions as consecutive reactions with alternating products. The results of the analytical peak-shape equations were compared with those from a numerical solution of the partial differential equation system modeling the chromatographic reactor. For small to medium conversions the correspondence was found to be sufficiently close to enable substitution of the numerical solution in fitting procedures for the determination of rate constants. Presented at the 21st ISC held in Stuttgart, Germany, 15th–20th September, 1996 |
| Keywords: | Chromatographic reactor First-order reversible reactions Analytical peak-shape equations |
| 本文献已被 SpringerLink 等数据库收录！ | |