Organic-inorganic hybrid compounds of Li with bisimidazole derivatives: Li ion binding study and topochemical properties |
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| Authors: | Hwang In-Chul Chandran R Prakash Singh N Jiten Khandelwal Manish Thangadurai T Daniel Lee Jung-Woo Chang Jeong Ah Kim Kwang S |
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| Institution: | Center for Superfunctional Materials, Department of Chemistry, Pohang University of Science and Technology, Pohang 790-784, Korea. spfe@postech.ac.kr |
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| Abstract: | The imidazole-based ligands, bis(imidazol-1-yl)methane (Bizm, 1a) and (pyrenyl)bis(imidazol-1-yl) methane (Pbizm,2a) were prepared. With LiClO4, these two compounds formed two novel organic-inorganic hybrid materials: a 3D network polymer Li(Bizm).ClO4 (1b) and a 1D chain polymer Li(Pbizm)2.ClO4 (2b). The intriguing topological and physiochemical characteristics of 1b and 2b are reported on the basis of the X-ray single-crystal structure analysis and Li ion binding studies. |
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