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一种由[Ag(CN)2]-和Mn(Ⅱ)建筑块组装的三个三维网穿插的超分子配合物的结构和荧光性质
引用本文:张建华,董文.一种由[Ag(CN)2]-和Mn(Ⅱ)建筑块组装的三个三维网穿插的超分子配合物的结构和荧光性质[J].无机化学学报,2006,22(6):1159-1162.
作者姓名:张建华  董文
作者单位:广州大学化学化工学院化学系,广州,510006
摘    要:0 Introduction Recently, a considerable effort on crystal engi- neering has been devoted to the research of supramolecular assemblies because they show abun- dant topologic structures and offer possibilities for po- tential applications of functional mate…

关 键 词:超分子配合物    亲银作用    荧光性
文章编号:1001-4861(2006)06-1159-04
收稿时间:2006-03-20
修稿时间:2006-04-29

Three Interpenetrating 3D Related Networks and Luminescence of a Supramolecular Assembly Containing [Ag(CN)2]- and Mn(Ⅱ) Tectons
ZHANG Jian-Hua and DONG Wen.Three Interpenetrating 3D Related Networks and Luminescence of a Supramolecular Assembly Containing [Ag(CN)2]- and Mn(Ⅱ) Tectons[J].Chinese Journal of Inorganic Chemistry,2006,22(6):1159-1162.
Authors:ZHANG Jian-Hua and DONG Wen
Institution:Department of Chemistry, School of Chemistry and Chemical Engineering, Guangzhou University, Guangzhou 510006 and Department of Chemistry, School of Chemistry and Chemical Engineering, Guangzhou University, Guangzhou 510006
Abstract:Three interpenetrating 3D related networks of a cyano-bridged heterometallic supramolecular complex {KMnAg(CN)2]3·H2O}n (1) have been synthesized, and characterized by single crystal X-ray diffraction. The solid state of 1 displays interesting luminescence determined by argentophilicity at room temperature. CCDC: 197205.
Keywords:supramolecular complex  argentophilicity  luminescence
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