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Syntheses based on nitrile oxides. 1. Reaction of aromatic nitrile oxides with N-cyanimides
Authors:V A Ogurtsov  O A Rakitin  N V Obruchnikova  L F Chertanova  A A Gazikasheva  L I Khmel'nitskii
Institution:(1) N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow
Abstract:The reaction of trialkylaminocyanimides with aromatic nitrile oxides leads to trialkylamino-(3-aryl-1,2,4-oxadiazol-5-yl)imides, while the corresponding reactions with sulfylcyanimines and phosphincyanimides do not take place. Using x-ray structural analysis the principal structural features of the 1,2,4-oxadiazole products have been elucidated.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2084–2089, September, 1990.
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