| 自制固相微萃取装置对水中5种农药残留量的分析 |
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| 引用本文： | 刘德仓,何娟,高会云,吕瑞鹤,程杰,卢奎. 自制固相微萃取装置对水中5种农药残留量的分析[J]. 分析试验室, 2009, 28(2) |
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| 作者姓名： | 刘德仓 何娟 高会云 吕瑞鹤 程杰 卢奎 |
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| 作者单位： | 河南工业大学化学化工学院,郑州,450001;河南工业大学化学化工学院,郑州,450001;河南工业大学化学化工学院,郑州,450001;河南工业大学化学化工学院,郑州,450001;河南工业大学化学化工学院,郑州,450001;河南工业大学化学化工学院,郑州,450001 |
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| 基金项目： | 河南省重大科技攻关项目，郑州市科技攻关项目 |
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| 摘 要： | 合成了一种丙烯酸酯聚合物,并将其作为固相微萃取涂层,使用自制的SPME装置和气质联用仪对水样中5种农药残留量进行分析,该装置制作简单、价格低廉.对影响分析灵敏度的各种实验因素进行了优化,在优化条件下分析5种农药标准样品质量浓度在1～1000 μg/L内与色谱峰面积呈良好的线性关系(r=0.995～0.999),检出限为0.391～1.170 ng/L.将自制涂层与商品涂层(PA)进行了比较,自制涂层对5种农药具有优良的吸附特性,较低的检出限.
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| 关 键 词： | 固相微萃取 丙烯酸酯共聚物 农药残留 |
Analysis of five pesticide residues in water samples by using laboratory-made solid-phase microextraction device |
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| LIU De-cang,HE Juan,GAO Hui-yun,L Rui-he,CHENG Jie,LU Kui. Analysis of five pesticide residues in water samples by using laboratory-made solid-phase microextraction device[J]. Chinese Journal of Analysis Laboratory, 2009, 28(2) |
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| Authors: | LIU De-cang HE Juan GAO Hui-yun L Rui-he CHENG Jie LU Kui |
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| Affiliation: | School of Chemistry and Chemical Engineering;Henan University of Technology;Zhengzhou 450001 |
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| Abstract: | An acrylate-based polymer was prepared and applied as a new fiber coating for solid-phase microextraction (SPME) for five pesticide residues from water samples. The efficiency of new coating was investigated by using a laboratory-made SPME device and gas chromatograph/mass spectrometer (GC/MS). The device was inexpensive and prepared simply. The optimum conditions for obtaining extraction efficiency, such as adsorption time and temperature, the desorption parameters, ionic strength and the pH values were in... |
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| Keywords: | Solid phase microextraction Acrylate-based polymer Pesticide residues |
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