n-Octane liquid-phase oxidation catalyzed by cobalt salts: Overall kinetic and product distribution |
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| Affiliation: | 1. Department of Earth Sciences, The Natural History Museum, London, SW7 5BD, United Kingdom;2. Department of Archaeogenetics, Max-Planck-Institute for the Science of Human History, Kahlaische Strasse 10, Jena, D-07745, Germany;3. Institute of Archaeology, University of Oxford, 36 Beaumont Street, Oxford, OX1 2PG, UK;4. MONREPOS Archaeological Research Centre and Museum for Human Behavioural Evolution, RGZM, Neuwied, Germany;1. Department of Family Medicine and Chronic Care, Vrije Universiteit Brussel, Brussels, Belgium;2. End-of-Life Care Research Group, Vrije Universiteit Brussel and Ghent University, Brussels, Belgium;3. Department of Family Medicine and Primary Health Care, Ghent University, Ghent, Belgium;4. Centre for Migration and Intercultural Studies, University of Antwerp, Antwerp, Belgium;2. Department of Pathology, Aichi Medical University Hospital, Nagakute, Japan;3. Department of Otolaryngology, Aichi Medical University, Nagakute, Japan |
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| Abstract: | n-Octane liquid-phase oxidation with oxygen-nitrogen mixtures homogeneously catalyzed by cobalt palmitate has been studied. The temperature (135 °C, 140 °C and 145 °C), the oxygen partial pressure (0.1 atm, 0.2 atm and 0.4 atm) and the catalyst concentration (1 ppm, 10 ppm and 100 ppm of Co) have been varied. An overall kinetic equation for the disappearance of hydrocarbon was determined and the influence of the experimental variables on the product distribution was analyzed. The ketone and alcohol isomers and acid distributions are also discussed. |
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