Oxidation Kinetics of Amorphous,Polycrystalline, and Nanocrystalline Co33Zr67 Alloys

The oxidation kinetics of amorphous, polycrystalline, and nanocrystalline CoZr₂ alloys have been studied under isothermal conditions in air atmosphere with a microbalance. DSC and X-ray diffraction were used to study the influence of oxidation on crystallization. The three alloys under investigation which have the same composition but differ in the microstructure showed noticeable differences in their oxidation behaviour: the oxidation of the amorphous alloy is characterized by a very fast initial oxygen absorption step, completed in less than 1–2 min, followed by a slow oxide growth obeying a logarithmic time law at 400 °C. The polycrystalline thermodynamically stable tetragonal alloy absorbs small amounts of oxygen and obeys a parabolic rate law in the temperature range 500–800 °C. The activation energy of oxygen diffusion in tetragonal CoZr₂ was determined from the temperature dependence of the parabolic rate constant. The intermediate nano-crystalline phase with a local structure more closely packed and ordered than that of the precursor amorphous phase, shows an oxidation behaviour similar to that of the tetragonal phase, but with a different time exponent.