Investigations into the Molecular Relaxation Processes in Lithium and Sodium Perchlorates by the Raman Scattering Method |
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Authors: | A. R. Aliev A. I. Akaeva A. Z. Gadzhiev |
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Affiliation: | (1) Kh. I. Amirkhanov Institute of Physics of the Far-East Scientific Center, Russian Academy of Sciences, Russia |
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Abstract: | The molecular relaxation processes in crystalline lithium and sodium perchlorates are investigated in the region of totally symmetric 1(A) ClO4–-anion oscillations by Raman light scattering spectroscopy. It is demonstrated that the reorientation in LiClO4 and NaClO4 represents an activation process. A premelting phase is detected for sodium perchlorate. |
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