| One Novel Vanadium-Phosphate Cluster [PV_(2.5)O_(8.5)]-3.83{H_2O} with Three-Dimensional Architecture |
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| 引用本文： | 刘颖,张宪玺,窦建民,王大奇,徐峰,周雷,苏怀敬. One Novel Vanadium-Phosphate Cluster [PV_(2.5)O_(8.5)]-3.83{H_2O} with Three-Dimensional Architecture[J]. 中国化学, 2006, 24(10): 1359-1362. DOI: 10.1002/cjoc.200690253 |
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| 作者姓名： | 刘颖 张宪玺 窦建民 王大奇 徐峰 周雷 苏怀敬 |
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| 作者单位： | College of Chemistry and Chemical Engineering Liaocheng University，Liaocheng，Shandong 252059，China，College of Chemistry and Chemical Engineering，Liaocheng University，Liaocheng，Shandong 252059，China，College of Chemistry and Chemical Engineering，Liaocheng University，Liaocheng，Shandong 252059，China，College of Chemistry and Chemical Engineering，Liaocheng University，Liaocheng，Shandong 252059，China，College of Chemistry and Chemical Engineering，Liaocheng University，Liaocheng，Shandong 252059，China，College of Chemistry and Chemical Engineering，Liaocheng University，Liaocheng，Shandong 252059，China，College of Chemistry and Chemical Engineering，Liaocheng University，Liaocheng，Shandong 252059，China |
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| 基金项目： | Project supported by the National Natural Science Foundation of China(No.20501011)，the Science Foundation of Liaocheng University(No.31801). |
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| 摘 要： | A novel vanadium-phosphate compound [PV_2.5O_8.5]·3.83{H_2O}(1)was obtained from the hydrothermal reac-tion and structurally characterized by elemental analysis and single-crystal X-ray diffraction,which exhibited thatthe title complex crystallized in cubic space group I-43m with crystal data:a=1.6115(1)nm,V=4.1848(1)nm~3,Z=12,D_c=1.783 g/cm~3,F(000)=2278,R_1=0.0528,and wR_2=0.1329[I>2σ(I)](all data).The basic unit of{PV_2.5O_8.5}symmetrically extended to closed sphere-like structure of{P_4V_(10)O_(34)},which was further linked to in-terleaving three-dimensional network via sharing four phosphate through μ_3-oxygen atoms around the closedsphere-like structures.
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One Novel Vanadium-Phosphate Cluster [PV_(2.5)O_(8.5)]-3.83{H_2O} with Three-Dimensional Architecture |
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| LIU Ying ZHANG Xian-Xi DOU Jian-Min WANG Da-Qi XU Feng ZHOU Lei SU Huai-Jing College of Chemistry and Chemical Engineering,Liaocheng University,Liaocheng,Shandong ,China. One Novel Vanadium-Phosphate Cluster [PV_(2.5)O_(8.5)]-3.83{H_2O} with Three-Dimensional Architecture[J]. Chinese Journal of Chemistry, 2006, 24(10): 1359-1362. DOI: 10.1002/cjoc.200690253 |
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| Authors: | LIU Ying ZHANG Xian-Xi DOU Jian-Min WANG Da-Qi XU Feng ZHOU Lei SU Huai-Jing College of Chemistry Chemical Engineering Liaocheng University Liaocheng Shandong China |
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| Affiliation: | LIU Ying~* ZHANG Xian-Xi DOU Jian-Min WANG Da-Qi XU Feng ZHOU Lei SU Huai-Jing College of Chemistry and Chemical Engineering,Liaocheng University,Liaocheng,Shandong 252059,China |
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| Abstract: | A novel vanadium‐phosphate compound [PV2.5O8.5]·3.83{H2O} ( 1 ) was obtained from the hydrothermal reaction and structurally characterized by elemental analysis and single‐crystal X‐ray diffraction, which exhibited that the title complex crystallized in cubic space group I‐43m with crystal data: a=1.6115(1) nm, V=4.1848(1) nm3,Z=12, Dc=1.783 g/cm3, F(000)=2278, R1=0.0528, and wR2=0.1329 [I>2σ(I)] (all data). The basic unit of {PV2.5O8.5} symmetrically extended to closed sphere‐like structure of {P4V10O34}, which was further linked to interleaving three‐dimensional network via sharing four phosphate through μ3‐oxygen atoms around the closed sphere‐like structures. |
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| Keywords: | vanadium-phosphate compound hydrothermal reaction X-ray diffraction |
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