One Novel Vanadium-Phosphate Cluster [PV_(2.5)O_(8.5)]-3.83{H_2O} with Three-Dimensional Architecture |
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| Authors: | LIU Ying ZHANG Xian-Xi DOU Jian-Min WANG Da-Qi XU Feng ZHOU Lei SU Huai-Jing College of Chemistry Chemical Engineering Liaocheng University Liaocheng Shandong China |
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| Affiliation: | LIU Ying~* ZHANG Xian-Xi DOU Jian-Min WANG Da-Qi XU Feng ZHOU Lei SU Huai-Jing College of Chemistry and Chemical Engineering,Liaocheng University,Liaocheng,Shandong 252059,China |
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| Abstract: | A novel vanadium‐phosphate compound [PV2.5O8.5]·3.83{H2O} ( 1 ) was obtained from the hydrothermal reaction and structurally characterized by elemental analysis and single‐crystal X‐ray diffraction, which exhibited that the title complex crystallized in cubic space group I‐43m with crystal data: a=1.6115(1) nm, V=4.1848(1) nm3,Z=12, Dc=1.783 g/cm3, F(000)=2278, R1=0.0528, and wR2=0.1329 [I>2σ(I)] (all data). The basic unit of {PV2.5O8.5} symmetrically extended to closed sphere‐like structure of {P4V10O34}, which was further linked to interleaving three‐dimensional network via sharing four phosphate through μ3‐oxygen atoms around the closed sphere‐like structures. |
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| Keywords: | vanadium-phosphate compound hydrothermal reaction X-ray diffraction |
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