Total synthesis and stereochemistry of (-)-cacospongionolide F |
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Authors: | Demeke Damtew Forsyth Craig J |
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Affiliation: | Department of Chemistry, University of Minnesota, 207 Pleasant Street SE, Minneapolis, Minnesota 55455, USA. |
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Abstract: | [reaction: see text] The most recently described member of the cacospongionolide class of marine natural products has been assembled using a diastereochemically divergent total synthesis strategy that independently establishes the complete stereochemistry of cacospongionolide F and provides a new entry toward expansion of this phospholipase A(2) inhibitor chemotype. |
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