Mathematical Simulation of the Synthesis of cis-1,4-Polybutadiene on a Cobalt-Containing Catalyst in the Presence of Ethylene |
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| Authors: | Aminova G. A. Manuiko G. V. Bronskaya V. V. Bronskii S. N. Ismagilova A. I. D'yakonov G. S. |
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| Affiliation: | (1) Kazan State Technological University, Kazan, 420015, Tatarstan, Russia |
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| Abstract: | Based on an analysis of experimental results and published data, the main elementary steps of the anionic coordination polymerization of butadiene rubber on a cobalt-containing catalyst in the presence of ethylene were found, and a mathematical model of the periodic process at an optimum water content was developed. The molecular-weight characteristics of the process depending on ethylene concentration were studied with the use of this model. |
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