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Reactions of styryl and phenylethynyl sulfones with some CH-acids
Authors:V A Vasin  I Yu Bolusheva  Yu Yu Masterova  V V Razin
Institution:1.Ogarev Mordovia State University,Saransk,Russia;2.St. Petersburg State University,St. Petersburg,Russia
Abstract:Reactions of methyl and p-tolyl phenylethynyl sulfones with enolated of dimethyl malonate and malononitrile lead to the formation of sulfonyl-substituted derivatives of ethylidenemalonic acid. Methyl (E)-β-styryl sulfone reacts with sodium enolates of dimethyl malonate, malononitrile, and methyl cyanoacetate to give common Michael adducts.
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