Synthesis of large surface area LaFeO3 nanoparticles by SBA-16 template method as high active visible photocatalysts |
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Authors: | Haijiao Su Liqiang Jing Keying Shi Changhao Yao and Honggang Fu |
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Institution: | (1) Key Laboratory of Functional Inorganic Materials Chemistry, Ministry of Education, Heilongjiang University, Harbin, 150080, People’s Republic of China; |
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Abstract: | Nanosized LaFeO3 with large specific surface area has been successfully synthesized by an impregnation process, with mesoporous silica SBA-16
as hard template and corresponding metal nitrates as La and Fe resources, and the resulting LaFeO3 is also characterized by thermogravimetry–differential thermal analysis (TG–DTA), X-ray diffraction (XRD), N2 adsorption–desorptions, Brunauer Emmett Teller (BET) technique, transmission electron microscopy (TEM), X-ray photoelectron
spectroscopy (XPS), UV–visible diffuse reflection spectrum (UV–Vis DRS), and surface photovoltage spectroscopy (SPS). It is
found that, compared with that prepared by the conventional citrate method, the as-prepared LaFeO3 with 20-50 nm particle size has remarkable large specific surface area, even still with the surface area as large as about
85 m2 g−1 after calcination at 800 °C, which is attributed to its mesoporous structure as well as the small particle size. During the
photocatalytic degradation of Rhodamine B solution under visible irradiation, all the LaFeO3 samples obtained are superior to P25 TiO2, and the activity becomes high with increasing calcination temperature. It is revealed that the excellent photocatalytic
performance is mainly ascribed to the large surface area and high photogenerated charge separation rate. |
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