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系统研究氢原子Stark能谱的数值方法Ⅱ—准稳态及其线型
引用本文:屈一至 姚德成. 系统研究氢原子Stark能谱的数值方法Ⅱ—准稳态及其线型[J]. 原子与分子物理学报, 1994, 11(2): 152-160
作者姓名:屈一至 姚德成
作者单位:中国科学院研究生院
摘    要:本文通过标度变换,引入t参量,将抛物坐标下分离变量后,稳定外电场下氢原子的Schrodinger方程消除了耦合,大大地简化了计算。由“有效动能”曲线给出“准稳态”存在的判据。利用波函数渐近表达式的周期性性质,可求出任意m值的氢原子能级随电场变化的解。本文以n=6时21条Stark分裂谱的E-F曲线为例,说明这种系统计算法的简便。最后通过边接出射波函数与其渐近形式,计算出散射振幅,分析了DC Sta

关 键 词:氢原子 斯塔克效应 数值计算

SYSTEMATIC NUMERICAL METHOD FOR STUDYING STARK SPECTRUM OF HYDROGEN ATOM -QUASI-STABLE STATE AND ITS PROFILE
Yizhi Qu and Decheng Yao. SYSTEMATIC NUMERICAL METHOD FOR STUDYING STARK SPECTRUM OF HYDROGEN ATOM -QUASI-STABLE STATE AND ITS PROFILE[J]. Journal of Atomic and Molecular Physics, 1994, 11(2): 152-160
Authors:Yizhi Qu and Decheng Yao
Abstract:Through scaling transformation of parameter t, the Schrodinger equations of hydrogen atom in DC electric field were decoupled in parabolic coordinate and the numerical calculation were dramatically simplified. The threshold for qusi-stable states is given by the effective kinetic energy. The DC stark energy of H of arbitary m and F can be obtained using the periodic property of the asymptotic expression of the wave function (WF). As an example, all the 21 stalk levels of n=6 stated are presented. The scattering amplitude is obtained by matching the out going WF and the asymptotic form, then the asymmetric DC stark profile can be achieved.
Keywords:Numerical Method   Stark effect   Hydrogen Atom.
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