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Dyeing of PA 6.6 fibers
Authors:Queirós Domingues  M S  Rocha Gomes  J I N  Martins  J A
Institution:(1) Departamento de Engenharia Tęxtil, Universidade do Minho, Campus de Azurém, 4800-058 Guimarăes, Portugal;(2) Universidade do Minho, Departamento de Engenharia de Polímeros, Campus de Azurém, 4800-058 Guimarăes, Portugal
Abstract:Dyeing fibers at low temperatures has many advantages such as savings in energy and avoiding alterations to the physical properties of the fibers being dyed or other fibers also present in blends. The problem of low temperature dyeing in synthetic fibers is that it difficults the dye diffusion into the fiber. In the case of polyamide 6.6 microfibers, by using benzyl alcohol as an auxiliary dyeing, it was shown that good diffusion was obtained for the dye exhaustion with metal complex dyes at temperatures more than 30°C below the normal dyeing temperature for the dye exhaustion with metal complex dyes. Using thermal analysis methods these results were shown to be caused by the lowering of the T g of the fiber when in the presence of benzyl alcohol. This revised version was published online in July 2006 with corrections to the Cover Date.
Keywords:polyamide  dyeing  benzyl alcohol  low temperature  microfibers
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