Photochemical Reaction between Tertiary Allylic Amines and Chromium Carbene Complexes: Synthesis of Lactams via a Zwitterion Aza Cope Rearrangement |
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| Authors: | Deur Christopher J Miller Michael W Hegedus Louis S |
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| Institution: | Department of Chemistry, Colorado State University, Fort Collins, Colorado 80523. |
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| Abstract: | Photolysis of chromium carbene complexes in the presence of tertiary allylic amines resulted in a zwitterionic aza Cope rearrangement to produce unsaturated lactams in fair yield. |
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