Rate constants for the reaction of OH radicals with CH3CN, C2H5CN AND CH2=CH-CN in the temperature range 298–424 K |
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| Authors: | G. W. Harris T. E. Kleindienst J. N. Pitts Jr. |
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| Affiliation: | Department of Chemistry and Statewide Air Pollution Research Center, University of California, Riverside, California 92521, USA |
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| Abstract: | Rate constants for the reactions of OH with CH3CN, CH3CH2CN and CH2=CH-CN have been measured to be 5.86 × 10−13 exp(−1500 ± 250 cal mole−1/RT), 2.69 × 10−13 exp(−1590 ± 350 cal mole−1/RT and 4.04 × 10−12 cm3 molecule−1 s−1, respectively in the temperature range 298–424 K. These results are discussed in terms of the atmospheric lifetimes of nitrfles. |
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| Keywords: | Address for correspondence: Chemistry Division Bhabha Atomic Research Centre Trombay Bombay-400 085 India. |
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