Synthesis of molecular magnetics based on cobalt trisoxalate. Structural and magnetic properties of NBun 4[MnIICoIII(C2O4)3] |
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| Authors: | N. A. Sanina G. V. Shilov N. S. Ovanesyan L. O. Atovmyan |
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| Affiliation: | (1) Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432 Chernoglolovka, Moscow Region, Russian Federation |
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| Abstract: | Bimetallic oxalate-bridged complexes Q[MIICo(C2O4)3] (Q=Me4N+, Bun 4P+; MII=Mn, Co, Ni, Cu, Zn) were synthesized. Single crystals of [NBun 4][MnIICoIII(C2O4)3] were studied by XRD. Unit cell parametersa=b=9.242(3) Å,c=54.524(13) Å; space groupR3c. Magnetic measurements indicate the absence of a magnetic phase transition up to the temperature of liquid helium. The XRD data confirm the presence of CoIII ions with a low-spin configuration in the crystal. |
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| Keywords: | synthesis bimetallic oxalates crystal and magnetic structure |
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