| 机械球磨共聚络合剂法制备Zn-Ni双金属催化剂催化环氧丙烷和领苯二甲酸酐共聚 |
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| 引用本文： | 赵洁,林强,朱祺东,石磊,董浩然. 机械球磨共聚络合剂法制备Zn-Ni双金属催化剂催化环氧丙烷和领苯二甲酸酐共聚[J]. 化学通报, 2016, 79(6): 523-527 |
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| 作者姓名： | 赵洁 林强 朱祺东 石磊 董浩然 |
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| 作者单位： | 海南师范大学化学与化工学院,海南师范大学,海南师范大学化学与化工学院,海南师范大学化学与化工学院,海南师范大学化学与化工学院 |
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| 基金项目： | 研究生创新科研课题(Hsyx2014-41) |
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| 摘 要： | 机械化学是一种快速且环境友好，具有巨大潜力的无溶剂合成双金属氰化物催化剂(DMC)的合成方法。共聚络合剂辅助机械球磨法成功制备出了Zn-Ni双金属催化剂。经元素分析和红外光谱表明双金属催化剂中掺入了各种共聚络合剂。扫描电镜表明，由此产生的双金属催化剂是纳米级的。双金属催化剂在无溶剂、反应时间为6h、反应温度为110°C的条件下对环氧丙烷(PO)与邻苯二甲酸酐(PA)的开环聚合是高效催化的。红外光谱、 1H-NMR 和 13C-NMR图谱均证明有聚酯(PO-co-PA)的结构。在共聚反应中，双金属催化剂显示相对较高的活性,得到了高产率、高分子量和窄分子量分布的聚酯(PO-co-PA）。
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| 关 键 词： | 锌-镍双金属催化剂，共聚络合剂，环氧丙烷，领苯二甲酸酐，球磨，共聚作用 |
| 收稿时间： | 2015-11-05 |
| 修稿时间： | 2016-01-27 |
Copolymerization of propylene oxide and phthalic anhydride catalyzed by Zn-Ni DMC with co-complexing agents incorporated via ball milling |
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| Zhao Jie,Lin Qiang,Zhu Qidong,Shi Lei and Dong Haoran. Copolymerization of propylene oxide and phthalic anhydride catalyzed by Zn-Ni DMC with co-complexing agents incorporated via ball milling[J]. Chemistry, 2016, 79(6): 523-527 |
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| Authors: | Zhao Jie Lin Qiang Zhu Qidong Shi Lei Dong Haoran |
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| Affiliation: | College of Chemistry and Chemical Engineering,Hainan Normal University,College of Chemistry and Chemical Engineering,Hainan Normal University,College of Chemistry and Chemical Engineering,Hainan Normal University,College of Chemistry and Chemical Engineering,Hainan Normal University,College of Chemistry and Chemical Engineering,Hainan Normal University |
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| Abstract: | Mechanochemistry as a rapid and environmentally friendly synthetic method emerges great potential in the solvent-free synthesis of double metal cyanide (DMC) catalysts. Zn-Ni DMCs with small amounts of co-complexing agents (co-CAs) were successfully synthesized during the grinding process. Elemental analysis and FT-IR indicated the incorporation of various co-CAs within DMCs. The SEM images showed that the resulting DMC catalysts were nanoscale. The DMC complex was proven to be an effective catalyst for the ring-open copolymerization of propylene oxide (PO) with phthalic anhydride (PA) without solvent under controlled reaction condition (6h, 110°C). IR, 1H-NMR and 13C-NMR confirmed the structure of poly (PO-co-PA). For copolymerization, the DMCs showed relatively high activity and the obtained polyester poly (PO-co-PA) exhibited high yields with high molecular weight and narrow polydispersity index. |
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| Keywords: | Zn-Ni double metal cyanide co-complexing agents propylene oxide phthalic anhydride ball milling copolymerization |
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