Reaction of palladium (I) carbonyl acetate with phosphorus-containing ligands and the molecular structure of tris(triphenylphosphine)palladium |
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| Authors: | T. A. Stromnova V. S. Sergienko A. V. Kisin M. A. Porai-Koshits I. I. Moiseev |
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| Affiliation: | (1) N. S. Kurnakov Institute of General and Inorganic Chemistry, Academy of Sciences of the USSR, Moscow;(2) State Scientific-Research Institute for the Chemistry and Technology of Hetero-organic Compounds, Moscow |
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| Abstract: | Conclusions Neutral and cationic carbonyl-containing palladium (II) complexes with phosphine ligands have been synthesized; they are not very stable in solution and undergo disproportionation to give palladium (0) and (II) compounds. The structure of one of these disproportionation products, namely, tris(triphenylphosphine)palladium, was solved by x-ray structural analysis.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 894–897, April, 1987. |
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