Copper complexes of a novel non-innocent quadridentate ligand |
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| Authors: | Buncic Gojko Xiao Zhiguang Drew Simon C White Jonathan M Wedd Anthony G Donnelly Paul S |
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| Institution: | School of Chemistry and Bio21 Molecular Science and Biotechnology Institute, University of Melbourne, Parkville, Victoria 3010, Australia. |
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| Abstract: | Quadridentate ligand H(2)L binds Cu(I) to form salt Cu(I)(H(2)L)]BF(4) which undergoes aerial oxidation in solution with isolation of the diamagnetic salt Cu(II)L˙(-)]BF(4) where π-radical anion L˙(-) is the (1e(-), 2H(+)) oxidation product of H(2)L. |
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