Magnetic effects in the reaction of benzyl chloride with triethylgermyl derivatives of alkali metals |
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| Authors: | T V Leshina V I Maryasova R Z Sagdeev O I Margorskaya D A Bravo-Zhivotovskii O A Kruglaya and N S Vyazankin |
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| Institution: | (1) Institute of Chemical Kinetics and Combustion, Novosibirsk Institute of Organic Chemistry, Irkutsk, USSR |
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| Abstract: | The reaction of benzyl chloride with triethylgermyllithium and its analogs have been studied by the1H-CIDNP method. A reaction mechanism is suggested. Benzyl and triethylgermyl free radicals have been found to be the precursors of main products. The magnetic field effects on the ratio of the main reaction products indicate that the radical path of their formation is predominant. The assumption is made that the ethylgermyl radicals take part in the reaction in the associated state.
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