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Catalysis of nucleophilic substitution reactions in supramolecular systems
Authors:Zakharova,L. Ya.,Mirgorodskaya,A. B.,Zhil"  tsova,E. P.,Kudryavtseva,L. A.,Konovalov,A. I.
Affiliation:(1) A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center of the Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420088 Kazan, Russian Federation. Fax
Abstract:The factors determining the catalytic effect of supramolecular systems on the nucleophilic substitution reactions are analyzed. The role of the structural and phase transitions of nanoaggregates in the catalytic mechanism are determined. The substrate specificity is shown for different structures of the supramolecular composition.
Keywords:supramolecular systems  catalysis  kinetics  nucleophilic substitution
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