Synthesis and structure of the 1,2-isopropylidene-α-D-glucofuranose 3,5,6-bis-cyclophosphite complex with tungsten(0) pentacarbonyl |
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| Authors: | T S Ulbaev Yu S Mardashev M P Koroteev V N Khrustalev M Yu Antipin |
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| Institution: | (1) Moscow State Pedagogical University, Moscow;(2) A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow |
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| Abstract: | Metallocomplexes with optically active ligands are of considerable interest as catalysts of stereoselective processes. A complex of 1,2-isopropylidene-α-D-glucofuranose 3,5,6-bis-cyclophosphite with tungsten(0) pentacarbonyl has been synthesized for the first time and studied by X-ray crystallography. |
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| Keywords: | metallocomplexes ligands optically active phosphites catalysts hydrocarbons |
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