| Structure of the Manganese (V) Complex-Mn·3/2(μ-DHBQ)·4H_2O·2Cl |
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| 作者单位： | Yi Xiang CHENG,Yun Chu WANG(Department of Chemistry & Chemical Engineering, Southeast University, Nanjing 210096);Mao Lin HU,Ji Xin YUAN(Department of Chemistry , Wenzhou Teachers College, Wenzhou 325003) |
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| 摘 要： | FewcompoundswithMninthe 5oxidationstatewerestructuraIlycharacterizedsofaLC.L.HilIlfirstdeterminedthecrystalstructUreoftheMn(V)complex:NMnTpMPP-Nitriodotrtrakis(p-methoxyphenyl)porphinnato-manganese(V).Thepapers'-'reportedseveralnovelmanganese(V)and(Vl)complexes.RecentpublicationshavebeenestablishedthatthecoordinationcompoundsofhighvaIentmanganesedisplaymanyinterestingfeatures.Theyshowabilitytoundergointramolecularinterligandormetal-ligandelectrontransferreaction,especiallyonthenatUreo…
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Structure of the Manganese (V) Complex-Mn.3/2(μ-DHBQ)·4H2O·2Cl |
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| Yi Xiang CHENG,Mao Lin HU,Ji Xin YUAN,Yun Chu WANG. Structure of the Manganese (V) Complex-Mn.3/2(μ-DHBQ)·4H2O·2Cl[J]. Chinese Chemical Letters, 2000, 11(7) |
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| Authors: | Yi Xiang CHENG Mao Lin HU Ji Xin YUAN Yun Chu WANG |
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| Abstract: | The novel complex of Mn(V): Mn·3/2(μ-DHBQ)·4H2O·2Cl (where, H2DHBQ = 2,5-dihydroxyl-1,4-benzoquinone) was synthesized and its crystal structure has been determined by X-ray diffraction. The complex belongs to trigonal system with space group P3(#147), a=1.415(2) nm, c=0.6552(4) nm, V=1.1371(7) nm-3, Z=2, Dx=1.183 g/cm3, μ=7.37 cm-1, F(000)=408.00, R=0.041, Rw=0.046. |
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| Keywords: | Manganese (V) crystal structure bridging ligand 2 5-dihydroxyl-1 4-benzoquinone |
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