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Reduction of Diaryldiselenides by System of Cp2TiCl2/ BuiMgBr/ THF and Its Application in Synthesis of Unsymmetrical Diaryl Selenides
Authors:Xin Hua XU  Xian Huang
Abstract:Reduction of diaryldiselenides by the system of Cp2TiCl2/Bu'MgBr/THF gave the nucleophilic arylselenium complex. They reacted with diaryl iodonium salts to afford unsymmetrical diaryl selenides in high yields.
Keywords:Diaryl selenides   reduction   titanocene dichloride   isobutylmagnesium bromide  arylselenium complex of titanocene   diaryl iodonium salts   unsymmetrical diaryl selenides
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