Structure-reactivity correlation in bromate oscillatory systems in aqueous-acetonitrile mixed medium |
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| Authors: | P V Lalitha and R Ramaswamy |
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| Institution: | (1) Department of Chemistry, Indian Institute of Technology, 600 036 Madras, India |
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| Abstract: | The oscillatory behavior of eight substrates has been studied in the uncatalyzed and catalyzed Mn(II) and ferroin] bromate systems in aqueous-acetonitrile mixed medium. The reactivities of structurally related compounds are correlated using their oscillatory characteristics. The exchange current density values of the redox couples involved play a vital role in deciding the oscillatory characteristics of the system. |
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