Planar chiral cyclic amine and its derivatives: synthesis and stereochemical behavior |
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| Authors: | Tomooka Katsuhiko Suzuki Masaki Shimada Maki Yanagitsuru Syun-ichi Uehara Kazuhiro |
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| Affiliation: | Department of Applied Chemistry, Graduate School of Science and Engineering, Tokyo Institute of Technology, Meguro-ku, Tokyo 152-8552, Japan. ktomooka@apc.titech.ac.jp |
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| Abstract: | [STRUCTURE: SEE TEXT] Nine-membered diallylic cyclic amines and amides have remarkably stable planar chirality. The transformation of enantiomerically enriched amides provides optically active nitrogen heterocycles containing stereogenic centers in a stereospecific fashion. |
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