Structure and reactivity of 2-amino-3-carbamoylchromone |
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Authors: | Sosnovskikh V Ya Kodess M I Moshkin V S |
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Institution: | 1.A. M. Gorky Ural State University, 51 prosp. Lenina, 620083, Ekaterinburg, Russian Federation ;2.I. Ya. Postovskii Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences, 22/20 ul. S. Kovalevskoi, 620041, Ekaterinburg, Russian Federation ; |
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Abstract: | The structure of 2-amino-3-carbamoylchromone has been studied by 1D and 2D NMR spectroscopy. Selective hydrolysis of this compound gives 3-carbamoyl-4-hydroxycoumarin, whereas the reactions with acetic anhydride and hydrazines, 2-methyl-4H-chromeno-2,3-d]pyrimidine-4,5(3H)-dione and 3-aminochromeno4,3-c]pyrazol-4-ones, respectively. |
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