Properties of n-butylpyridinium nitrate ionic liquid and its binary mixtures with water |
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Authors: | Jian-ying Wang Xiang-jing Zhang Yong-qi Hu Guo-di Qi Li-ya Liang |
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Institution: | College of Chemical and Pharmaceutical Engineering, Hebei University of Science and Technology, 70 Yuhua East Road, Shijiazhuang 050018, PR China |
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Abstract: | The density and surface tension of the pure ionic liquid n-butylpyridinium nitrate (BuPy]NO3) were determined at temperature range from T = (293.15 to 338.15) K. The coefficient of thermal expansion, molecular volume and lattice energy of BuPy]NO3 were calculated from the experimental values of density. The surface entropy and enthalpy of BuPy]NO3 were investigated. The IL studied show much lower surface enthalpy and lattice energy in comparison with fused salts. The densities and surface tensions of binary mixtures of BuPy]NO3 with water have been measured within the whole composition range at T = 298.15 K and atmospheric pressure. Excess molar volumes VE and surface tension deviations δγ were then deduced from the experimental results as well as partial molar volumes and excess partial molar volumes. Excess molar volumes have a negative deviation from ideal behavior and the surface tension deviations are negative over the whole compositions range. VE and δγ were correlated with suitable equation respectively. |
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