Unusual reaction of triazole derivatives with 1-iodomethyl-1,1,3,3,3-pentamethyldisiloxane |
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Authors: | Shagun L G Dorofeev I A Zhilitskaya L V Yarosh N O Larina L I |
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Institution: | 1.A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 ul. Favorskogo, 664033, Irkutsk, Russian Federation ; |
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Abstract: | The solvent-free reaction of 1-iodomethyl-1,1,3,3,3-pentamethyldisiloxane with 1,2,4-triazole derivatives and 1,2,3-benzotriazole afforded organylcyclosiloxane iodides and triiodides. The reactions involved alkylation of pyridine and pyrrole nitrogens and cleavage of the siloxane bonds mediated by hydrogen iodide generated upon the reaction. |
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