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Unusual reaction of triazole derivatives with 1-iodomethyl-1,1,3,3,3-pentamethyldisiloxane
Authors:Shagun  L G  Dorofeev  I A  Zhilitskaya  L V  Yarosh  N O  Larina  L I
Institution:1.A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 ul. Favorskogo, 664033, Irkutsk, Russian Federation
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Abstract:

The solvent-free reaction of 1-iodomethyl-1,1,3,3,3-pentamethyldisiloxane with 1,2,4-triazole derivatives and 1,2,3-benzotriazole afforded organylcyclosiloxane iodides and triiodides. The reactions involved alkylation of pyridine and pyrrole nitrogens and cleavage of the siloxane bonds mediated by hydrogen iodide generated upon the reaction.

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