Hexanuclear chloride and brimode tungsten clusters and their derivatives |
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| Authors: | P. A. Abramov A. V. Rogachev M. A. Mikhailov A. V. Virovets E. V. Peresypkina M. N. Sokolov V. P. Fedin |
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| Affiliation: | 1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of Russian Academy of Sciences, Novosibirsk, Russia
2. Novosibirsk State University, Novosibirsk, Russia
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| Abstract: | Several hexanuclear chloride and bromide bridged tungsten clusters have been prepared. Two new oxo-bridged clusters, Na[W6OBr18] and [α-W6(μ2-OH)4(μ2-O)6(μ2-Cl)2Cl6]2? are reported. Crystal structures of eight new tungsten cluster complexes with different core types were determined. The possibility of Se for Cl substitution in the {W6Cl8}4+ core was investigated. |
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