Neutral pion photoproduction off nucleons revisited

We investigate threshold pion photoproduction in the framework of heavy baryon chiral perturbation theory. We give the expansion of the electric dipole amplitude E ₀₊ to three orders in μ the ratio of the pion to nucleon mass, and show that it is slowly converging. We argue that this observable is not a good testing ground for the chiral dynamics of QCD. In contrast, we exhibit new and fastly converging low-energy theorems in the P-waves which should be used to constrain the data analysis. We also discuss the importance of polarization observables to accurately pin down certain multipoles and give predictions for the reaction γ n → π⁰ n.