Kinetics of heat-induced and photochemical transformations of quinonimines and their derivatives |
| |
Authors: | O G Mishchenko I V Spirina S V Maslennikov A V Piskunov I N Meshcheryakova S V Panteleev R V Kroik |
| |
Institution: | 1. Research Institute of Chemistry, Nizhni Novgorod Lobachevsky State University, pr. Gagarina 23, kor. 3, Nizhni Novgorod, 603950, Russia 2. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhni Novgorod, Russia
|
| |
Abstract: | Heat-induced transformations of N-2,6-diisopropylphenyl]-3,5-di(tert-butyl)-, N-2,6-diethylphenyl]-3,5-di(tert-butyl)-, and N-2-methyl-6-ethylphenyl]-3,5-di(tert-butyl)-o-benzoquinonimines in nonane follow the first-order rate equation, whereas that of N-2,5-di(tert-butyl)phenyl]-3,5-di(tert-butyl-o-benzoquinonimine obey the second-order rate equation. Kinetic parameters of these reactions have been determined. 4aH-Phenoxazine derivatives of quinonimines are intermediates of the heat-induced transformations following the first-order kinetics; under the irradiation with 405 nm light they undergo the ring opening to give the starting compounds with quantum yield close to unity. |
| |
Keywords: | |
本文献已被 SpringerLink 等数据库收录! |
|